Be aware that you may have to use some strong chemicals. It is a good idea to consult with a specialist before using chemicals, especially if you are using septic systems. It is bad idea to use chlorine bleach, it only sets the iron stain. Usually the rust stains can be removed with oxalic acid solution.

The Works is another chemical cleaner good for removing rust stains. It very easy to use, just spray it on the rusty surface, let it set and rinse it. Be VERY CAREFUL because the product contains about 20% hydrochloric acid and can be dangerous and never use it for septic systems.
For around $10, you can buy Shaw’s Pads Toilet Ring Remover. These pads are safe for septic systems because they do not use chemicals. They are very easy to use, you just have to wet the pad and use short vigorous strokes. Then the scale and staining comes free from the porcelain.
To remove small rust stains you can use salty lemon. First, pour a pile of table salt on top of the rust stain and then squeeze lemon juice over it. This pile of salty lemon juice must stay for several hours. When it is ready, you will probably see the rust in this pile of salt and lemon juice.
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